TY - JOUR
T1 - Application of UVOX Redox (R) for swimming pool water treatment
T2 - Microbial inactivation, disinfection byproduct formation and micropollutant removal
AU - Ekowati, Yuli
AU - Ferrero, Giuliana
AU - Farré, Maria José
AU - Kennedy, Maria D.
AU - Buttiglieri, Gianluigi
PY - 2019
Y1 - 2019
N2 - Alternative disinfection technologies may overcome some of the limitations of conventional treatment applied in swimming pools: chlorine-resistant pathogens (e.g. Cryptosporidium oocysts and Giardia cysts) and the formation of chlorinated disinfection byproducts. In this paper, results of full scale validation of an alternative disinfection technology UVOX Redox® (hereinafter referred to as UVOX) that combines ozonation and UV irradiation are presented. The performance was assessed in terms of microbial inactivation, disinfection byproduct formation and micropollutant removal. UVOX was able to achieve 1.4–2.7 log inactivation of Bacillus subtilis spores at water flows between 20 and 76 m³/h. Lower formation of trichloromethane and dichloroacetic acid was observed with UVOX followed by chlorination when compared to chlorination alone. However, due to the use of ozone and the presence of bromide in the pool water, the formation of trihalomethanes and haloacetic acids shifted to more brominated byproducts. Chlorine alone was able to remove the target micropollutants: acetaminophen, atenolol, caffeine, carbamazepine, estrone, estradiol, and venlafaxine (>97% removal) after 24 h, with the exception of ibuprofen (60% removal). The application of UVOX in chlorinated water enhanced the removal of ibuprofen. The application of UVOX could lower the usage of chlorine to the level that provides an adequate residual disinfection effect.
AB - Alternative disinfection technologies may overcome some of the limitations of conventional treatment applied in swimming pools: chlorine-resistant pathogens (e.g. Cryptosporidium oocysts and Giardia cysts) and the formation of chlorinated disinfection byproducts. In this paper, results of full scale validation of an alternative disinfection technology UVOX Redox® (hereinafter referred to as UVOX) that combines ozonation and UV irradiation are presented. The performance was assessed in terms of microbial inactivation, disinfection byproduct formation and micropollutant removal. UVOX was able to achieve 1.4–2.7 log inactivation of Bacillus subtilis spores at water flows between 20 and 76 m³/h. Lower formation of trichloromethane and dichloroacetic acid was observed with UVOX followed by chlorination when compared to chlorination alone. However, due to the use of ozone and the presence of bromide in the pool water, the formation of trihalomethanes and haloacetic acids shifted to more brominated byproducts. Chlorine alone was able to remove the target micropollutants: acetaminophen, atenolol, caffeine, carbamazepine, estrone, estradiol, and venlafaxine (>97% removal) after 24 h, with the exception of ibuprofen (60% removal). The application of UVOX in chlorinated water enhanced the removal of ibuprofen. The application of UVOX could lower the usage of chlorine to the level that provides an adequate residual disinfection effect.
KW - Bacillus subtilis spore
KW - Disinfection
KW - Disinfection byproducts
KW - Endocrine disruptors
KW - Pharmaceuticals
UR - http://www.scopus.com/inward/record.url?scp=85058817971&partnerID=8YFLogxK
U2 - 10.1016/j.chemosphere.2018.12.126
DO - 10.1016/j.chemosphere.2018.12.126
M3 - Article
AN - SCOPUS:85058817971
SN - 0045-6535
VL - 220
SP - 176
EP - 184
JO - Chemosphere
JF - Chemosphere
ER -