Abstract
The use of micron sized nanoporous diatom algae exoskeletons for inhibitor storage and sustained corrosion protection of coated aluminium structures upon damage is presented. In this concept the algae exoskeleton allows local inhibitor loading, limits the interaction between the cerium and the epoxy/amine coating and allows for diffusion-controlled release of the inhibitor when needed. The inhibitor release and corrosion protection by loaded exoskeletons was evaluated by UV/Vis spectrometry, a home-built optical-electrochemical setup, and Raman spectroscopy. Although this concept has been proven for a cerium-epoxy-aluminium alloy system the main underlying principle can be extrapolated to other inhibitor-coating-metal systems.
Original language | English |
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Pages (from-to) | 164-175 |
Number of pages | 12 |
Journal | Corrosion Science: the journal on environmental degradation of materials and its control |
Volume | 128 |
DOIs | |
Publication status | Published - 1 Nov 2017 |
Keywords
- AA2024
- Anticorrosion
- Biosilica
- Cerium
- Coating
- Corrosion Inhibitor
- Diatomaceous Earth
- EIS
- Inhibition
- Microcarrier
- Raman