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Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers. / Bose, Ranjita K.; Enke, Marcel; Grande, Antonio M.; Zechel, Stefan; Schacher, Felix H.; Hager, Martin D.; Garcia, Santiago J.; Schubert, Ulrich S.; van der Zwaag, Sybrand.

In: European Polymer Journal, Vol. 93, 01.08.2017, p. 417-427.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Bose, RK, Enke, M, Grande, AM, Zechel, S, Schacher, FH, Hager, MD, Garcia, SJ, Schubert, US & van der Zwaag, S 2017, 'Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers', European Polymer Journal, vol. 93, pp. 417-427. https://doi.org/10.1016/j.eurpolymj.2017.06.020

APA

Bose, R. K., Enke, M., Grande, A. M., Zechel, S., Schacher, F. H., Hager, M. D., Garcia, S. J., Schubert, U. S., & van der Zwaag, S. (2017). Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers. European Polymer Journal, 93, 417-427. https://doi.org/10.1016/j.eurpolymj.2017.06.020

Vancouver

Bose RK, Enke M, Grande AM, Zechel S, Schacher FH, Hager MD et al. Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers. European Polymer Journal. 2017 Aug 1;93:417-427. https://doi.org/10.1016/j.eurpolymj.2017.06.020

Author

Bose, Ranjita K. ; Enke, Marcel ; Grande, Antonio M. ; Zechel, Stefan ; Schacher, Felix H. ; Hager, Martin D. ; Garcia, Santiago J. ; Schubert, Ulrich S. ; van der Zwaag, Sybrand. / Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers. In: European Polymer Journal. 2017 ; Vol. 93. pp. 417-427.

BibTeX

@article{63dd89ae53944fd38fcef739ca4bf0a0,
title = "Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers",
abstract = "The main aim of this work is to study the respective contribution of the hard and soft blocks of a metal-ligand containing block copolymer to the self-healing behavior. To this aim, different block copolymers containing terpyridine were synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization. These block copolymers consisted of polystyrene as the hard block, n-butyl acrylate (BA) as soft block and terpyridine units as the ligand moiety placed at different locations in the soft block. These block copolymers were complexed with manganese(II) chloride to introduce transient crosslinks and, thus, self-healing behavior. Homopolymers with the hard and soft block only were also synthesized and tested. A quasi-irreversible crosslinking, i.e. by using nickel(II) nitrate, was performed in order to study the dynamics of the permanently (strongly) crosslinked network. Rheological master curves were generated enabling the determination of the terminal flow in these networks and the reversibility of the supramolecular interactions. Additionally, the macroscopic scratch healing behavior and the molecular mobility of the polymer chains in these supramolecular networks were investigated. A kinetic study of the scratch healing was performed to determine the similarities in temperature dependence for rheological relaxations and macroscopic scratch healing. In our previous work, we have explored the effect of strength of the reversible metal-ligand interaction and the effect of changing the ratio of hard to soft block. This work goes further in separating the individual contributions of the hard and soft blocks as well as the reversible interactions and to reveal their relative importance in the complex phenomenon of scratch healing.",
keywords = "Block-copolymer, Metallopolymer, Rheology, Self-healing polymer, Supramolecular network",
author = "Bose, {Ranjita K.} and Marcel Enke and Grande, {Antonio M.} and Stefan Zechel and Schacher, {Felix H.} and Hager, {Martin D.} and Garcia, {Santiago J.} and Schubert, {Ulrich S.} and {van der Zwaag}, Sybrand",
year = "2017",
month = aug,
day = "1",
doi = "10.1016/j.eurpolymj.2017.06.020",
language = "English",
volume = "93",
pages = "417--427",
journal = "European Polymer Journal",
issn = "0014-3057",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Contributions of hard and soft blocks in the self-healing of metal-ligand-containing block copolymers

AU - Bose, Ranjita K.

AU - Enke, Marcel

AU - Grande, Antonio M.

AU - Zechel, Stefan

AU - Schacher, Felix H.

AU - Hager, Martin D.

AU - Garcia, Santiago J.

AU - Schubert, Ulrich S.

AU - van der Zwaag, Sybrand

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The main aim of this work is to study the respective contribution of the hard and soft blocks of a metal-ligand containing block copolymer to the self-healing behavior. To this aim, different block copolymers containing terpyridine were synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization. These block copolymers consisted of polystyrene as the hard block, n-butyl acrylate (BA) as soft block and terpyridine units as the ligand moiety placed at different locations in the soft block. These block copolymers were complexed with manganese(II) chloride to introduce transient crosslinks and, thus, self-healing behavior. Homopolymers with the hard and soft block only were also synthesized and tested. A quasi-irreversible crosslinking, i.e. by using nickel(II) nitrate, was performed in order to study the dynamics of the permanently (strongly) crosslinked network. Rheological master curves were generated enabling the determination of the terminal flow in these networks and the reversibility of the supramolecular interactions. Additionally, the macroscopic scratch healing behavior and the molecular mobility of the polymer chains in these supramolecular networks were investigated. A kinetic study of the scratch healing was performed to determine the similarities in temperature dependence for rheological relaxations and macroscopic scratch healing. In our previous work, we have explored the effect of strength of the reversible metal-ligand interaction and the effect of changing the ratio of hard to soft block. This work goes further in separating the individual contributions of the hard and soft blocks as well as the reversible interactions and to reveal their relative importance in the complex phenomenon of scratch healing.

AB - The main aim of this work is to study the respective contribution of the hard and soft blocks of a metal-ligand containing block copolymer to the self-healing behavior. To this aim, different block copolymers containing terpyridine were synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization. These block copolymers consisted of polystyrene as the hard block, n-butyl acrylate (BA) as soft block and terpyridine units as the ligand moiety placed at different locations in the soft block. These block copolymers were complexed with manganese(II) chloride to introduce transient crosslinks and, thus, self-healing behavior. Homopolymers with the hard and soft block only were also synthesized and tested. A quasi-irreversible crosslinking, i.e. by using nickel(II) nitrate, was performed in order to study the dynamics of the permanently (strongly) crosslinked network. Rheological master curves were generated enabling the determination of the terminal flow in these networks and the reversibility of the supramolecular interactions. Additionally, the macroscopic scratch healing behavior and the molecular mobility of the polymer chains in these supramolecular networks were investigated. A kinetic study of the scratch healing was performed to determine the similarities in temperature dependence for rheological relaxations and macroscopic scratch healing. In our previous work, we have explored the effect of strength of the reversible metal-ligand interaction and the effect of changing the ratio of hard to soft block. This work goes further in separating the individual contributions of the hard and soft blocks as well as the reversible interactions and to reveal their relative importance in the complex phenomenon of scratch healing.

KW - Block-copolymer

KW - Metallopolymer

KW - Rheology

KW - Self-healing polymer

KW - Supramolecular network

UR - http://www.scopus.com/inward/record.url?scp=85020922675&partnerID=8YFLogxK

UR - http://resolver.tudelft.nl/uuid:63dd89ae-5394-4fd3-8fce-f739ca4bf0a0

U2 - 10.1016/j.eurpolymj.2017.06.020

DO - 10.1016/j.eurpolymj.2017.06.020

M3 - Article

AN - SCOPUS:85020922675

VL - 93

SP - 417

EP - 427

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

ER -

ID: 22084618