Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

S Sachdeva, A. Pustovarenko, EJR Sudholter, F Kapteijn, LCPM de Smet, J Gascon

Research output: Contribution to journalArticleScientificpeer-review

25 Citations (Scopus)
27 Downloads (Pure)

Abstract



A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.



Graphical abstract: Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis

Original languageEnglish
Pages (from-to)4018-4022
Number of pages5
JournalCrystEngComm
DOIs
Publication statusPublished - 2016

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