Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells

R. Torres-Cavanillas; L. Lima-Moya; F. D. Tichelaar; H. W. Zandbergen; M. Giménez-Marqués; E. Coronado

doi:10.1039/c9dt02086a

Downsizing of robust Fe-triazole@SiO₂ spin-crossover nanoparticles with ultrathin shells

R. Torres-Cavanillas, L. Lima-Moya, F. D. Tichelaar, H. W. Zandbergen, M. Giménez-Marqués^*, E. Coronado

^*Corresponding author for this work

Research output: Contribution to journal › Article › Scientific › peer-review

19 Citations (Scopus)

Abstract

A chemical protocol to design robust hybrid [Fe(Htrz)₂(trz)](BF₄)@SiO₂ nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.

Original language	English
Pages (from-to)	15465-15469
Journal	Dalton Transactions
Volume	48
Issue number	41
DOIs	https://doi.org/10.1039/c9dt02086a
Publication status	Published - 2019

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title = "Downsizing of robust Fe-triazole@SiO2 spin-crossover nanoparticles with ultrathin shells",

abstract = "A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.",

author = "R. Torres-Cavanillas and L. Lima-Moya and Tichelaar, {F. D.} and Zandbergen, {H. W.} and M. Gim{\'e}nez-Marqu{\'e}s and E. Coronado",

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AU - Torres-Cavanillas, R.

AU - Lima-Moya, L.

AU - Tichelaar, F. D.

AU - Zandbergen, H. W.

AU - Giménez-Marqués, M.

AU - Coronado, E.

PY - 2019

Y1 - 2019

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AB - A chemical protocol to design robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2 nanoparticles (NPs) with sizes as small as 28 nm and ultrathin silica shells below 3 nm has been developed. These NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Downsizing of robust Fe-triazole@SiO₂ spin-crossover nanoparticles with ultrathin shells

Abstract

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