TY - JOUR
T1 - Efficiency and durability of g-C3N4-based coatings applied on mortar under peeling and washing trials
AU - Yang, Yu
AU - Ji, Tao
AU - Yang, Zhengxian
AU - Zhang, Yong
AU - Su, Wenyue
AU - Wu, Ronghan
AU - Wu, Zehao
N1 - Accepted Author Manuscript
PY - 2020
Y1 - 2020
N2 - Durability of photocatalytic coatings is a major concern in engineering practice. Here, two types of novel visible light-responsive coatings, both consisting of vinyl chloride/vinyl ester/ethylene copolymer (as a binder) and graphitic carbon nitride (g-C3N4) but different in fabrication, are proposed and applied on the mortar surface. The first type is mono-layer coating (MC), where the g-C3N4 suspension containing the binder is directly sprayed on the mortar. The second type is double-layer coating (DC), where the binder layer is applied on mortar surface before spraying the g-C3N4 layer. Results show that the binder addition leads to a good anchorage of the coatings on both MC and DC mortar substrates, along with desirable resistance to peeling and washing, compared to the g-C3N4 coated mortar without the binder. The well-distributed binder in g-C3N4-based coating inevitably decreases the photocatalytic efficiency of the MC mortar due to masking effect of the binder on the coating surface. The DC mortar, on the contrary, takes full advantage of the binder adhesion by inserting a binder layer and therefore holds strong resistance to peeling and washing without compromising its photocatalytic efficiency. The proposed DC technique provides a promising strategy to fabricate highly cost-effective and durable photocatalytic coatings applied on cementitious materials.
AB - Durability of photocatalytic coatings is a major concern in engineering practice. Here, two types of novel visible light-responsive coatings, both consisting of vinyl chloride/vinyl ester/ethylene copolymer (as a binder) and graphitic carbon nitride (g-C3N4) but different in fabrication, are proposed and applied on the mortar surface. The first type is mono-layer coating (MC), where the g-C3N4 suspension containing the binder is directly sprayed on the mortar. The second type is double-layer coating (DC), where the binder layer is applied on mortar surface before spraying the g-C3N4 layer. Results show that the binder addition leads to a good anchorage of the coatings on both MC and DC mortar substrates, along with desirable resistance to peeling and washing, compared to the g-C3N4 coated mortar without the binder. The well-distributed binder in g-C3N4-based coating inevitably decreases the photocatalytic efficiency of the MC mortar due to masking effect of the binder on the coating surface. The DC mortar, on the contrary, takes full advantage of the binder adhesion by inserting a binder layer and therefore holds strong resistance to peeling and washing without compromising its photocatalytic efficiency. The proposed DC technique provides a promising strategy to fabricate highly cost-effective and durable photocatalytic coatings applied on cementitious materials.
KW - Durability
KW - g-CN-based coatings
KW - Mortar substrate
KW - Photocatalytic NO removal
UR - http://www.scopus.com/inward/record.url?scp=85074629726&partnerID=8YFLogxK
U2 - 10.1016/j.conbuildmat.2019.117438
DO - 10.1016/j.conbuildmat.2019.117438
M3 - Article
AN - SCOPUS:85074629726
SN - 0950-0618
VL - 234
JO - Construction and Building Materials
JF - Construction and Building Materials
M1 - 117438
ER -