Standard

Electrochemistry of zirconium in molten chlorides. / Xu, Liang; Xiao, Yanping; Xu, Qian; Song, Qiushi; Yang, Yongxiang.

In: International Journal of Electrochemical Science, Vol. 12, No. 7, 2017, p. 6393-6403.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Xu, L, Xiao, Y, Xu, Q, Song, Q & Yang, Y 2017, 'Electrochemistry of zirconium in molten chlorides' International Journal of Electrochemical Science, vol. 12, no. 7, pp. 6393-6403. https://doi.org/10.20964/2017.07.51

APA

Xu, L., Xiao, Y., Xu, Q., Song, Q., & Yang, Y. (2017). Electrochemistry of zirconium in molten chlorides. International Journal of Electrochemical Science, 12(7), 6393-6403. https://doi.org/10.20964/2017.07.51

Vancouver

Xu L, Xiao Y, Xu Q, Song Q, Yang Y. Electrochemistry of zirconium in molten chlorides. International Journal of Electrochemical Science. 2017;12(7):6393-6403. https://doi.org/10.20964/2017.07.51

Author

Xu, Liang ; Xiao, Yanping ; Xu, Qian ; Song, Qiushi ; Yang, Yongxiang. / Electrochemistry of zirconium in molten chlorides. In: International Journal of Electrochemical Science. 2017 ; Vol. 12, No. 7. pp. 6393-6403.

BibTeX

@article{16eb02a392084235804d2e7b18db36dd,
title = "Electrochemistry of zirconium in molten chlorides",
abstract = "In this work, the electrochemical behavior of zirconium was studied on an inert molybdenum electrode at 550 °C in a LiCl-KCl-K2ZrF6 molten salt system, which is considered as an ideal electrolyte for the zirconium electrorefining process. Several transient electrochemical techniques were used such as cyclic voltammetry, chronopotentiometry, square wave voltammetry, and open circuit chronopotentiometry. The reduction of Zr (IV) was determined to follow a two-step mechanism of Zr (IV)/Zr (II) and Zr (II)/Zr. The diffusion coefficient of Zr (IV) was investigated with cyclic voltammetry and chronopotentiometry, and the results turned out to be in fair agreement from the both methods, as to be 4.26×10-5 and 4.98×10-5 cm2/s, respectively. The present study aims to provide a theoretical reference for the Zr electrorefining process.",
keywords = "Electrochemistry, Molten salt, Redox mechanism, Zirconium",
author = "Liang Xu and Yanping Xiao and Qian Xu and Qiushi Song and Yongxiang Yang",
year = "2017",
doi = "10.20964/2017.07.51",
language = "English",
volume = "12",
pages = "6393--6403",
journal = "International Journal of Electrochemical Science",
issn = "1452-3981",
publisher = "Electrochemical Science Group",
number = "7",

}

RIS

TY - JOUR

T1 - Electrochemistry of zirconium in molten chlorides

AU - Xu, Liang

AU - Xiao, Yanping

AU - Xu, Qian

AU - Song, Qiushi

AU - Yang, Yongxiang

PY - 2017

Y1 - 2017

N2 - In this work, the electrochemical behavior of zirconium was studied on an inert molybdenum electrode at 550 °C in a LiCl-KCl-K2ZrF6 molten salt system, which is considered as an ideal electrolyte for the zirconium electrorefining process. Several transient electrochemical techniques were used such as cyclic voltammetry, chronopotentiometry, square wave voltammetry, and open circuit chronopotentiometry. The reduction of Zr (IV) was determined to follow a two-step mechanism of Zr (IV)/Zr (II) and Zr (II)/Zr. The diffusion coefficient of Zr (IV) was investigated with cyclic voltammetry and chronopotentiometry, and the results turned out to be in fair agreement from the both methods, as to be 4.26×10-5 and 4.98×10-5 cm2/s, respectively. The present study aims to provide a theoretical reference for the Zr electrorefining process.

AB - In this work, the electrochemical behavior of zirconium was studied on an inert molybdenum electrode at 550 °C in a LiCl-KCl-K2ZrF6 molten salt system, which is considered as an ideal electrolyte for the zirconium electrorefining process. Several transient electrochemical techniques were used such as cyclic voltammetry, chronopotentiometry, square wave voltammetry, and open circuit chronopotentiometry. The reduction of Zr (IV) was determined to follow a two-step mechanism of Zr (IV)/Zr (II) and Zr (II)/Zr. The diffusion coefficient of Zr (IV) was investigated with cyclic voltammetry and chronopotentiometry, and the results turned out to be in fair agreement from the both methods, as to be 4.26×10-5 and 4.98×10-5 cm2/s, respectively. The present study aims to provide a theoretical reference for the Zr electrorefining process.

KW - Electrochemistry

KW - Molten salt

KW - Redox mechanism

KW - Zirconium

UR - http://resolver.tudelft.nl/uuid:16eb02a3-9208-4235-804d-2e7b18db36dd

UR - http://www.scopus.com/inward/record.url?scp=85023746964&partnerID=8YFLogxK

U2 - 10.20964/2017.07.51

DO - 10.20964/2017.07.51

M3 - Article

VL - 12

SP - 6393

EP - 6403

JO - International Journal of Electrochemical Science

T2 - International Journal of Electrochemical Science

JF - International Journal of Electrochemical Science

SN - 1452-3981

IS - 7

ER -

ID: 22858688