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A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an IrIIICp∗-based catalyst for the hydrogen production from formic acid and (2) a PtII-based catalyst for the direct activation of methane via Periana chemistry. The immobilized catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF-based catalysts can be further optimized by engineering at different length scales.

Original languageEnglish
Pages (from-to)26060-26065
Number of pages6
JournalACS Applied Materials and Interfaces
Volume9
Issue number31
DOIs
Publication statusPublished - 9 Aug 2017

    Research areas

  • covalent triazine frameworks, hydrogen, methane, methanol, structured catalysts

ID: 26525026