TY - JOUR
T1 - Facile Method for the Preparation of Covalent Triazine Framework coated Monoliths as Catalyst Support
T2 - Applications in C1 Catalysis
AU - Bavykina, Anastasiya V.
AU - Olivos-Suarez, Alma I.
AU - Osadchii, Dmitrii
AU - Valecha, Rahul
AU - Franz, Robert
AU - Makkee, Michiel
AU - Kapteijn, Freek
AU - Gascon, Jorge
PY - 2017/8/9
Y1 - 2017/8/9
N2 - A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an IrIIICp∗-based catalyst for the hydrogen production from formic acid and (2) a PtII-based catalyst for the direct activation of methane via Periana chemistry. The immobilized catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF-based catalysts can be further optimized by engineering at different length scales.
AB - A quasi chemical vapor deposition method for the manufacture of well-defined covalent triazine framework (CTF) coatings on cordierite monoliths is reported. The resulting supported porous organic polymer is an excellent support for the immobilization of two different homogeneous catalysts: (1) an IrIIICp∗-based catalyst for the hydrogen production from formic acid and (2) a PtII-based catalyst for the direct activation of methane via Periana chemistry. The immobilized catalysts display a much higher activity in comparison with the unsupported CTF operated in slurry because of improved mass transport. Our results demonstrate that CTF-based catalysts can be further optimized by engineering at different length scales.
KW - covalent triazine frameworks
KW - hydrogen
KW - methane
KW - methanol
KW - structured catalysts
UR - http://resolver.tudelft.nl/uuid:8ae4cd13-7da9-4c2b-b8ed-1432b825337b
UR - http://www.scopus.com/inward/record.url?scp=85027218205&partnerID=8YFLogxK
U2 - 10.1021/acsami.7b07339
DO - 10.1021/acsami.7b07339
M3 - Article
AN - SCOPUS:85027218205
SN - 1944-8244
VL - 9
SP - 26060
EP - 26065
JO - ACS Applied Materials and Interfaces
JF - ACS Applied Materials and Interfaces
IS - 31
ER -
