Metal-organic framework-mediated synthesis in catalysis

Lide Oar-Arteta Gonzalez; Tim Wezendonk; Xiaohui Sun; Freek Kapteijn; Jorge Gascon

doi:10.1002/9783527699827

Metal-organic framework-mediated synthesis in catalysis

Lide Oar-Arteta Gonzalez, Tim Wezendonk, Xiaohui Sun, Freek Kapteijn, Jorge Gascon

ChemE/Catalysis Engineering

Research output: Chapter in Book/Conference proceedings/Edited volume › Chapter › Scientific

Abstract

The dehydration of glycerol into acrolein was investigated over small‐sized γ‐Al2O3 prepared by a metal–organic framework (MOF) templated method. The particle size of alumina strongly affected the final physicochemical properties of γ‐Al2O3 as well as its catalytic activity. The MOF‐derived, small‐sized γ‐Al2O3 (M‐Al2O3) catalyst exhibited higher stability and higher activity in the glycerol dehydration reaction than conventional bulk γ‐Al2O3 and nanorod γ‐Al2O3 owing to enriched intercrystal mesopores and an abundance of accessible acid sites. M‐Al2O3 retained its high glycerol conversion (over 80 %) for nearly 200 h, whereas high acrolein selectivity (74 %) was achieved.

Original language	English
Title of host publication	Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection
Subtitle of host publication	Preparation of nanocatalysts and their potential in catalysis
Editors	Bert Sels, Marcel Van de Voorde
Publisher	Wiley
Pages	225-250
Volume	1
ISBN (Electronic)	978-3-527-69982-7
ISBN (Print)	978-3-527-33914-3
DOIs	https://doi.org/10.1002/9783527699827
Publication status	Published - 2017

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10.1002/9783527699827

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Oar-Arteta Gonzalez, L., Wezendonk, T., Sun, X., Kapteijn, F., & Gascon, J. (2017). Metal-organic framework-mediated synthesis in catalysis. In B. Sels, & M. Van de Voorde (Eds.), Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection: Preparation of nanocatalysts and their potential in catalysis (Vol. 1, pp. 225-250). Wiley. https://doi.org/10.1002/9783527699827

Oar-Arteta Gonzalez, Lide ; Wezendonk, Tim ; Sun, Xiaohui et al. / Metal-organic framework-mediated synthesis in catalysis. Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection: Preparation of nanocatalysts and their potential in catalysis. editor / Bert Sels ; Marcel Van de Voorde. Vol. 1 Wiley, 2017. pp. 225-250

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title = "Metal-organic framework-mediated synthesis in catalysis",

abstract = "The dehydration of glycerol into acrolein was investigated over small‐sized γ‐Al2O3 prepared by a metal–organic framework (MOF) templated method. The particle size of alumina strongly affected the final physicochemical properties of γ‐Al2O3 as well as its catalytic activity. The MOF‐derived, small‐sized γ‐Al2O3 (M‐Al2O3) catalyst exhibited higher stability and higher activity in the glycerol dehydration reaction than conventional bulk γ‐Al2O3 and nanorod γ‐Al2O3 owing to enriched intercrystal mesopores and an abundance of accessible acid sites. M‐Al2O3 retained its high glycerol conversion (over 80 %) for nearly 200 h, whereas high acrolein selectivity (74 %) was achieved. ",

author = "{Oar-Arteta Gonzalez}, Lide and Tim Wezendonk and Xiaohui Sun and Freek Kapteijn and Jorge Gascon",

year = "2017",

doi = "10.1002/9783527699827",

language = "English",

isbn = "978-3-527-33914-3",

volume = "1",

pages = "225--250",

editor = "Bert Sels and {Van de Voorde}, Marcel",

booktitle = "Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection",

publisher = "Wiley",

}

Oar-Arteta Gonzalez, L, Wezendonk, T, Sun, X, Kapteijn, F & Gascon, J 2017, Metal-organic framework-mediated synthesis in catalysis. in B Sels & M Van de Voorde (eds), Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection: Preparation of nanocatalysts and their potential in catalysis. vol. 1, Wiley, pp. 225-250. https://doi.org/10.1002/9783527699827

Metal-organic framework-mediated synthesis in catalysis. / Oar-Arteta Gonzalez, Lide; Wezendonk, Tim; Sun, Xiaohui et al.
Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection: Preparation of nanocatalysts and their potential in catalysis. ed. / Bert Sels; Marcel Van de Voorde. Vol. 1 Wiley, 2017. p. 225-250.

Research output: Chapter in Book/Conference proceedings/Edited volume › Chapter › Scientific

TY - CHAP

T1 - Metal-organic framework-mediated synthesis in catalysis

AU - Oar-Arteta Gonzalez, Lide

AU - Wezendonk, Tim

AU - Sun, Xiaohui

AU - Kapteijn, Freek

AU - Gascon, Jorge

PY - 2017

Y1 - 2017

N2 - The dehydration of glycerol into acrolein was investigated over small‐sized γ‐Al2O3 prepared by a metal–organic framework (MOF) templated method. The particle size of alumina strongly affected the final physicochemical properties of γ‐Al2O3 as well as its catalytic activity. The MOF‐derived, small‐sized γ‐Al2O3 (M‐Al2O3) catalyst exhibited higher stability and higher activity in the glycerol dehydration reaction than conventional bulk γ‐Al2O3 and nanorod γ‐Al2O3 owing to enriched intercrystal mesopores and an abundance of accessible acid sites. M‐Al2O3 retained its high glycerol conversion (over 80 %) for nearly 200 h, whereas high acrolein selectivity (74 %) was achieved.

AB - The dehydration of glycerol into acrolein was investigated over small‐sized γ‐Al2O3 prepared by a metal–organic framework (MOF) templated method. The particle size of alumina strongly affected the final physicochemical properties of γ‐Al2O3 as well as its catalytic activity. The MOF‐derived, small‐sized γ‐Al2O3 (M‐Al2O3) catalyst exhibited higher stability and higher activity in the glycerol dehydration reaction than conventional bulk γ‐Al2O3 and nanorod γ‐Al2O3 owing to enriched intercrystal mesopores and an abundance of accessible acid sites. M‐Al2O3 retained its high glycerol conversion (over 80 %) for nearly 200 h, whereas high acrolein selectivity (74 %) was achieved.

U2 - 10.1002/9783527699827

DO - 10.1002/9783527699827

M3 - Chapter

SN - 978-3-527-33914-3

VL - 1

SP - 225

EP - 250

BT - Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection

A2 - Sels, Bert

A2 - Van de Voorde, Marcel

PB - Wiley

ER -

Oar-Arteta Gonzalez L, Wezendonk T, Sun X, Kapteijn F, Gascon J. Metal-organic framework-mediated synthesis in catalysis. In Sels B, Van de Voorde M, editors, Nanotechnology in catalysis: Applications in the chemical industry, energy development, and environment protection: Preparation of nanocatalysts and their potential in catalysis. Vol. 1. Wiley. 2017. p. 225-250 doi: 10.1002/9783527699827

Metal-organic framework-mediated synthesis in catalysis

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