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Quantitative study on dissolution behavior of Nd2O3 in fluoride melts. / Guo, Xiaoling; Sun, Zhi; Sietsma, Jilt; Blanpain, Bart; Guo, Muxing; Yang, Yongxiang.

In: Industrial and Engineering Chemistry Research, Vol. 57, No. 5, 2018, p. 1380-1388.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Guo, X, Sun, Z, Sietsma, J, Blanpain, B, Guo, M & Yang, Y 2018, 'Quantitative study on dissolution behavior of Nd2O3 in fluoride melts' Industrial and Engineering Chemistry Research, vol. 57, no. 5, pp. 1380-1388. https://doi.org/10.1021/acs.iecr.7b04125

APA

Guo, X., Sun, Z., Sietsma, J., Blanpain, B., Guo, M., & Yang, Y. (2018). Quantitative study on dissolution behavior of Nd2O3 in fluoride melts. Industrial and Engineering Chemistry Research, 57(5), 1380-1388. https://doi.org/10.1021/acs.iecr.7b04125

Vancouver

Guo X, Sun Z, Sietsma J, Blanpain B, Guo M, Yang Y. Quantitative study on dissolution behavior of Nd2O3 in fluoride melts. Industrial and Engineering Chemistry Research. 2018;57(5):1380-1388. https://doi.org/10.1021/acs.iecr.7b04125

Author

Guo, Xiaoling ; Sun, Zhi ; Sietsma, Jilt ; Blanpain, Bart ; Guo, Muxing ; Yang, Yongxiang. / Quantitative study on dissolution behavior of Nd2O3 in fluoride melts. In: Industrial and Engineering Chemistry Research. 2018 ; Vol. 57, No. 5. pp. 1380-1388.

BibTeX

@article{a48929fabf5c4d2c886f3d58a4b2ed37,
title = "Quantitative study on dissolution behavior of Nd2O3 in fluoride melts",
abstract = "The dissolution of rare earth oxides in molten fluorides is a critical step in the preparation of the corresponding rare earth metals by oxide-fluoride electrolysis. However, quantitatively understanding the nature of dissolution, especially in the case of molten salts, is usually difficult to be achieved by postmortem characterization. In this paper, the dissolution behavior of Nd2O3 particles in molten fluorides was studied via in situ observation with confocal scanning laser microscopy. Combining direct observation with thermodynamic analyses on the oxide dissolution, the rate-limiting step(s) and the effects of parameters like temperature, salt type, and composition on the dissolution rate are identified. This study provides a methodology to estimate the dissolution kinetics of rare earth oxides in molten fluorides during their primary and secondary processing.",
author = "Xiaoling Guo and Zhi Sun and Jilt Sietsma and Bart Blanpain and Muxing Guo and Yongxiang Yang",
year = "2018",
doi = "10.1021/acs.iecr.7b04125",
language = "English",
volume = "57",
pages = "1380--1388",
journal = "Industrial and Engineering Chemistry Research",
issn = "0888-5885",
publisher = "American Chemical Society (ACS)",
number = "5",

}

RIS

TY - JOUR

T1 - Quantitative study on dissolution behavior of Nd2O3 in fluoride melts

AU - Guo, Xiaoling

AU - Sun, Zhi

AU - Sietsma, Jilt

AU - Blanpain, Bart

AU - Guo, Muxing

AU - Yang, Yongxiang

PY - 2018

Y1 - 2018

N2 - The dissolution of rare earth oxides in molten fluorides is a critical step in the preparation of the corresponding rare earth metals by oxide-fluoride electrolysis. However, quantitatively understanding the nature of dissolution, especially in the case of molten salts, is usually difficult to be achieved by postmortem characterization. In this paper, the dissolution behavior of Nd2O3 particles in molten fluorides was studied via in situ observation with confocal scanning laser microscopy. Combining direct observation with thermodynamic analyses on the oxide dissolution, the rate-limiting step(s) and the effects of parameters like temperature, salt type, and composition on the dissolution rate are identified. This study provides a methodology to estimate the dissolution kinetics of rare earth oxides in molten fluorides during their primary and secondary processing.

AB - The dissolution of rare earth oxides in molten fluorides is a critical step in the preparation of the corresponding rare earth metals by oxide-fluoride electrolysis. However, quantitatively understanding the nature of dissolution, especially in the case of molten salts, is usually difficult to be achieved by postmortem characterization. In this paper, the dissolution behavior of Nd2O3 particles in molten fluorides was studied via in situ observation with confocal scanning laser microscopy. Combining direct observation with thermodynamic analyses on the oxide dissolution, the rate-limiting step(s) and the effects of parameters like temperature, salt type, and composition on the dissolution rate are identified. This study provides a methodology to estimate the dissolution kinetics of rare earth oxides in molten fluorides during their primary and secondary processing.

UR - http://www.scopus.com/inward/record.url?scp=85042022626&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.7b04125

DO - 10.1021/acs.iecr.7b04125

M3 - Article

VL - 57

SP - 1380

EP - 1388

JO - Industrial and Engineering Chemistry Research

T2 - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 5

ER -

ID: 40378152