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Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid. / Bavykina, Anastasiya V.; Rozhko, Elena; Goesten, Maarten G.; Wezendonk, Tim; Seoane, B.; Kapteijn, Freek; Makkee, Michiel; Gascon, J.

In: ChemCatChem, Vol. 8, No. 13, 06.07.2016, p. 2217-2221.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Bavykina, AV, Rozhko, E, Goesten, MG, Wezendonk, T, Seoane, B, Kapteijn, F, Makkee, M & Gascon, J 2016, 'Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid', ChemCatChem, vol. 8, no. 13, pp. 2217-2221. https://doi.org/10.1002/cctc.201600419

APA

Vancouver

Bavykina AV, Rozhko E, Goesten MG, Wezendonk T, Seoane B, Kapteijn F et al. Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid. ChemCatChem. 2016 Jul 6;8(13):2217-2221. https://doi.org/10.1002/cctc.201600419

Author

Bavykina, Anastasiya V. ; Rozhko, Elena ; Goesten, Maarten G. ; Wezendonk, Tim ; Seoane, B. ; Kapteijn, Freek ; Makkee, Michiel ; Gascon, J. / Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid. In: ChemCatChem. 2016 ; Vol. 8, No. 13. pp. 2217-2221.

BibTeX

@article{37ee796c168548538cb88b692499f891,
title = "Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid",
abstract = "A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.",
keywords = "carbon dioxide hydrogenation, catalyst shaping, covalent triazine frameworks, formic acid",
author = "Bavykina, {Anastasiya V.} and Elena Rozhko and Goesten, {Maarten G.} and Tim Wezendonk and B. Seoane and Freek Kapteijn and Michiel Makkee and J. Gascon",
note = "Accepted Author Manuscript",
year = "2016",
month = jul,
day = "6",
doi = "10.1002/cctc.201600419",
language = "English",
volume = "8",
pages = "2217--2221",
journal = "ChemCatChem",
issn = "1867-3880",
publisher = "Wiley-VCH",
number = "13",

}

RIS

TY - JOUR

T1 - Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

AU - Bavykina, Anastasiya V.

AU - Rozhko, Elena

AU - Goesten, Maarten G.

AU - Wezendonk, Tim

AU - Seoane, B.

AU - Kapteijn, Freek

AU - Makkee, Michiel

AU - Gascon, J.

N1 - Accepted Author Manuscript

PY - 2016/7/6

Y1 - 2016/7/6

N2 - A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.

AB - A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.

KW - carbon dioxide hydrogenation

KW - catalyst shaping

KW - covalent triazine frameworks

KW - formic acid

UR - http://resolver.tudelft.nl/uuid:37ee796c-1685-4853-8cb8-8b692499f891

UR - http://www.scopus.com/inward/record.url?scp=84970991027&partnerID=8YFLogxK

U2 - 10.1002/cctc.201600419

DO - 10.1002/cctc.201600419

M3 - Article

AN - SCOPUS:84970991027

VL - 8

SP - 2217

EP - 2221

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

IS - 13

ER -

ID: 7931716