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  • c7dt02110k

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DOI

  • Denis Bykov
  • R.J.M. Konings
  • C. Apostolidis
  • A. Hen
  • E Colineau
  • T Wiss
  • P. Raison
A new double neptunium zirconium phosphate of the type MxZr2(PO4)3 (M = Np), crystallizing in the structure type NaZr2(PO4)3 (NZP, NASICON), was synthesized by solid state reactions at high temperatures and characterized by X-ray diffraction, infrared spectroscopy and Mössbauer spectroscopy. The Rietveld refinement of the XRD pattern together with the analysis of the IR spectra of the sample confirmed the space group P[3 with combining macron]c, the same as that for the lanthanide analogues Ln0.33Zr2(PO4)3. However, Mössbauer studies revealed the presence of neptunium in the two oxidation states +3 and +4, indicating a two-phase NZP system with different crystallographic environments of the neptunium atoms. The thermal behaviour of the sample was followed up to 1400 °C by thermogravimetric analysis.
Original languageEnglish
Pages (from-to)11626-11635
JournalDalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry
Volume46
Issue number35
DOIs
Publication statusPublished - 23 Aug 2017

ID: 26737938