DOI

  • Bin Gu
  • Chenglin Sun
  • James C. Fettinger
  • William H. Casey
  • Alla Dikhtiarenko
  • Jorge Gascon
  • Kamila Koichumanova
  • Karthick Babu Sai Sankar Gupta
  • Hero Jan Heeres
  • Songbo He

Herein we present the first example of a glycol-coordinated ϵ-Keggin Al13 chloride (gl-ϵ-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

Original languageEnglish
Pages (from-to)4148-4151
JournalChemical Communications
Volume54
Issue number33
DOIs
Publication statusPublished - 2018
Externally publishedYes

ID: 47183849