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ZIF-67 as silver-bullet in adsorptive propane/propylene separation. / Andres-Garcia, Eduardo; Oar-Arteta, Lide; Gascon, Jorge; Kapteijn, Freek.

In: Chemical Engineering Journal, Vol. 360, 2019, p. 10-14.

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Harvard

Andres-Garcia, E, Oar-Arteta, L, Gascon, J & Kapteijn, F 2019, 'ZIF-67 as silver-bullet in adsorptive propane/propylene separation', Chemical Engineering Journal, vol. 360, pp. 10-14. https://doi.org/10.1016/j.cej.2018.11.118

APA

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Author

Andres-Garcia, Eduardo ; Oar-Arteta, Lide ; Gascon, Jorge ; Kapteijn, Freek. / ZIF-67 as silver-bullet in adsorptive propane/propylene separation. In: Chemical Engineering Journal. 2019 ; Vol. 360. pp. 10-14.

BibTeX

@article{c54e4a9cc0ca40aeb057926d0b7fccea,
title = "ZIF-67 as silver-bullet in adsorptive propane/propylene separation",
abstract = "The cobalt-based ZIF-67 has been evaluated for the adsorptive propylene/propane separation in a fixed bed. Characterization techniques and dynamic measurements have been performed over ZIF-67 to evaluate its potential in this defiant process. Cobalt promotes a more rigid framework than zinc in the isostructural ZIF-8. Although the adsorption affinity of ZIF-67 for both hydrocarbons is similar, the lower flexibility of the framework makes ZIF-67 behave with a clear preference towards propane. This inverse selectivity promotes the enrichment in propylene content upon breakthrough, and may simplify the separation scheme. Therefore, ZIF-67 adsorptive separation is presented as an alternative to energy-demanding distillation.",
keywords = "Adsorption, Propane, Propylene, Separation, Zeolitic Imidazolate Framework, ZIF-67",
author = "Eduardo Andres-Garcia and Lide Oar-Arteta and Jorge Gascon and Freek Kapteijn",
year = "2019",
doi = "10.1016/j.cej.2018.11.118",
language = "English",
volume = "360",
pages = "10--14",
journal = "Chemical Engineering Journal",
issn = "1385-8947",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - ZIF-67 as silver-bullet in adsorptive propane/propylene separation

AU - Andres-Garcia, Eduardo

AU - Oar-Arteta, Lide

AU - Gascon, Jorge

AU - Kapteijn, Freek

PY - 2019

Y1 - 2019

N2 - The cobalt-based ZIF-67 has been evaluated for the adsorptive propylene/propane separation in a fixed bed. Characterization techniques and dynamic measurements have been performed over ZIF-67 to evaluate its potential in this defiant process. Cobalt promotes a more rigid framework than zinc in the isostructural ZIF-8. Although the adsorption affinity of ZIF-67 for both hydrocarbons is similar, the lower flexibility of the framework makes ZIF-67 behave with a clear preference towards propane. This inverse selectivity promotes the enrichment in propylene content upon breakthrough, and may simplify the separation scheme. Therefore, ZIF-67 adsorptive separation is presented as an alternative to energy-demanding distillation.

AB - The cobalt-based ZIF-67 has been evaluated for the adsorptive propylene/propane separation in a fixed bed. Characterization techniques and dynamic measurements have been performed over ZIF-67 to evaluate its potential in this defiant process. Cobalt promotes a more rigid framework than zinc in the isostructural ZIF-8. Although the adsorption affinity of ZIF-67 for both hydrocarbons is similar, the lower flexibility of the framework makes ZIF-67 behave with a clear preference towards propane. This inverse selectivity promotes the enrichment in propylene content upon breakthrough, and may simplify the separation scheme. Therefore, ZIF-67 adsorptive separation is presented as an alternative to energy-demanding distillation.

KW - Adsorption

KW - Propane

KW - Propylene

KW - Separation

KW - Zeolitic Imidazolate Framework

KW - ZIF-67

UR - http://www.scopus.com/inward/record.url?scp=85057278282&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2018.11.118

DO - 10.1016/j.cej.2018.11.118

M3 - Article

AN - SCOPUS:85057278282

VL - 360

SP - 10

EP - 14

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

SN - 1385-8947

ER -

ID: 47700442